====== AlCl₃ (Aluminum Chloride) ====== **Chemical formula**: AlCl₃ **Common name**: Aluminum chloride **Molar mass**: 133.34 g/mol **Appearance**: White to yellowish crystalline solid (anhydrous) or colorless solution (hydrated) **Density**: 2.44 g/cm³ (anhydrous) **Melting point**: 192.4 °C (anhydrous, sublimates) **Boiling point**: 180 °C (decomposes) ===== 🧪 Chemical Properties ===== * Highly hygroscopic — absorbs water from air and forms **AlCl₃·6H₂O** * Acts as a **Lewis acid** — strong electron pair acceptor * Forms covalent bonds in vapor/gas phase, but ionic in hydrated form * Reacts violently with water, releasing heat and hydrochloric acid ===== ⚗️ Uses ===== * **Catalyst** in Friedel–Crafts alkylation and acylation reactions * **Polymerization catalyst** in petrochemical industry * Used in manufacture of **rubber, lubricants, dyes, and pharmaceuticals** * Etching agent in **metallurgy and electronics** ===== ☣️ Safety and Hazards ===== * **Corrosive** to skin, eyes, and mucous membranes * Inhalation of fumes can cause respiratory tract irritation * Reacts exothermically with water → handle with extreme care * Store in **dry, airtight containers** away from moisture ===== 🔬 Industrial Notes ===== * Commonly used in **anhydrous form** for organic synthesis * Hydrated form (AlCl₃·6H₂O) is more stable but less reactive in catalytic applications * In the presence of moisture, releases HCl fumes ===== 📚 References ===== * [[https://pubchem.ncbi.nlm.nih.gov/compound/Aluminum-chloride|PubChem: Aluminum Chloride]] * [[https://www.chemeurope.com/en/encyclopedia/Aluminium_chloride.html|Chemeurope: Aluminium Chloride]]